Download Analytical Applications of EDTA and Related Compounds by R. Přibil, R. Belcher, H. Freiser PDF

By R. Přibil, R. Belcher, H. Freiser

Analytical purposes of EDTA and comparable Compounds examines the analytical purposes of ethylenediaminetetra-acetic acid (EDTA) and comparable compounds. This e-book additionally considers the “passive” position of those ingredients, that's, their screening (masking) homes, which significantly increase the selectivity of the reactions in universal use.
This textual content includes six chapters geared up into sections. the 1st half bargains with the makes use of of EDTA and its derivatives in a few fields of chemical research. After offering an summary of the heritage at the back of the improvement of EDTA as an analytical reagent, this publication discusses to the character of equilibria of complexes and the tools utilized in their research. the subsequent bankruptcy is devoted to the reactions of “classical” gravimetric research, together with the precipitation reactions via natural reagents. The bankruptcy on colorimetry incorporates a part on “colored complexing agents,” which are used additionally in colorimetric determinations of a few components. this article concludes via comparing using EDTA as a covering agent in colorimetry.
This e-book could be of curiosity to scholars and practitioners operating in analytical chemistry and similar disciplines, together with polarography, chromatography, electrophoresis, flame photometry, and qualitative research.

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Analytical Applications of EDTA and Related Compounds

Analytical purposes of EDTA and similar Compounds examines the analytical purposes of ethylenediaminetetra-acetic acid (EDTA) and similar compounds. This ebook additionally considers the “passive” position of those ingredients, that's, their screening (masking) homes, which drastically enhance the selectivity of the reactions in universal use.

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T h e radioactivity of the precipitate will be proportional t o their concentration. The additional danger was an exchange reaction between the nickel salt a n d the complex, and an enhanced radioactivity of the precipitate. Evidence for this was the find­ ing of larger radioactivity of the hydroxide when a longer period was allowed between the mixing of the complex with Ni chloride solution and precipitation of the hydroxide. The radioactivity of the samples was therefore extrapolated to the moment of mixing and the value obtained was used to calculate the free metal ion concentration; the stability constant obtained on this basis was Κ^^^γ = 10^^, which is in good agreement with that given by Schwarzenbach (10^^) [62].

CH2 O . CH2 . CH2 . HN> :H2 . CH2/ THE NATURE OF EQUILIBRIA OF COMPLEXES AND METHODS OF STUDY 43 XI. Bis-2-aminoethylether-Ar,iV,A^',iV'-tetra-acetic acid [23]. Dissociation constants and stability con­ stants measured at 20°C and μ = 0-1 in KNO3. (pK^ = 1-9; = 2-67; pKs = 8-82; püC^ = 9-49) TABLE Cation Complex logi^^Y Cation Compiex lOg^MY Mg2+ Ca^^ Ba2+ Mn^^ MgY^CaY^BaY^ΜηΥ2- 8-3 10-0 8-2 13-2 Cu2+ Zn2+ Cd2+ CuY^ΖηΥ2CdY^- 17-8 15-3 17-8 T A B L E XII. l,2-bis-i5-aminoethoxyethane-MA^,^',A^'-tetra-acetic acid [23].

51. 52. 53. 54. SCHWARZENBACH, G . and SCHWARZENBACH, G . and SCHWARZENBACH, G . and BRU-, K . and KRUMHOLZ, SANDERA, J . , Helv. chim. acta 3 1 , 4 5 9 ( 1 9 4 8 ) . BIEDERMANN, W . , Helv. chim. acta 3 1 , 4 5 9 ( 1 9 4 8 ) . F R E O A G , E . , Helv. chim. acta 3 4 , 1 5 0 3 ( 1 9 5 1 ) . P . , / . Phys. Chem. 5 8 , 3 3 9 ( 1 9 5 4 ) . 55. 56. 57. 58. KOLTHOFF, L M . and AUERBACH, C , / . Am. Chem. Soc. 7 4 , 1 4 5 2 ( 1 9 5 2 ) . BLUMER, M . and KOLTHOFF, I . , Experientia 8 , 1 3 8 ( 1 9 5 2 ) .

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